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Here is an easy way to change out your emoticons without too much work.
Simply delete the emoticon you want to switch from any folder it may be in , images folders in the Emotify plugin. Then rename the images you wish to place the same name as the ones you deleted. Upload those to the images folder. Go to the css file and change only the width and height values of the emoticon you changed so it appears the correct size on post.
Here is a link to where I changed the last three emoticons with others. http://mydatabass.com/Forum/discussion/2/why-not-promote-yourself-#Item_2